Many organic acids as well as inorganic salts were found to enrich the color density at 520nm of anthocyanin solution (pH 3.0) from juice of Campbell Early grapes and to stabilize the enriched color density for a long period (forty days).
(1) On saturated
n-monocarboxylic acid (0.2M), a linear relations existed between the number of carbon atoms (carboxylic acid) and the logarithmic value of ΔE
520nm. Thus, it was proved that the hyperchromic effect enhanced with increasing the molecular weight.
(2) On the polycarboxylic acids tested, a linear relation was also obtained between the concentration of acids and ΔE
520nm. Maleic acid showed the most hyperchromic effect.
(3) Many organic acids maintained the increasing of available pigment concentration during storage.
(4) The organic acids were classified into three groups by the effect on the pigment solution during storage as follows: (i) The first group such as maleic and
n-valeric acids; the more hyperchromic effect and favorably maintaining the effect. (ii) The second group such as tartaric and citric acids; the smaller hyperchromic effect and retaining the effect. (iii) The last group such as malonic and oxalic acids; the hyperchromic effect close to the first group but decolorizing the pigment solution.
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