Gel strength, swellings power, syneresis and amylographic behaviour of potato-starch gels with nonionic surfactants were studied to know the effects of the surfactants on the aging of starch. All the surfactants employed in this investigation have an antistaling effect, namely, both of increase rate in the gel strength and decrease rate in the swelling power with time are lower than those of the control gel without surfactant. Especially, gel strength of the gels with more hydrophilic surfactants slowly increases.
The gels with hydrophilic surfactants, however, showed remarkable syneresis, which might suggest remarkable aging of starch.
Whereas, according to the amylographic behaviour at the time to prepare the sample gels in which syneresis appear easily, the gelatinization temperature is high and maximum viscosity is low. These results suggested that the interaction between the hydrophilic surfactants and the starch are fairly strong.
Inconsequence, it is seemed that the syneresis of starch gel is not necessarily caused by the aging, but caused by the decreased hydration power of the complex with hydrophilic surfactant and starch, and the strong hydrogen bond of intracomplex. At the same time, H-bonds of interstarch chain are disturbed by the occurrence of the H-bond of intracomplex, resulting in the restraint of the aging of starch.
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