Journal of Japan Society for Safety Engineering
Online ISSN : 2424-0656
Print ISSN : 0570-4480
ISSN-L : 0570-4480
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Volume 32, Issue 3
JOURNAL OF JAPAN SOCIETY FOR SAFETY ENGINEERING_1993_3
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PROPOSAL FOR SAFETY
REVIEW
  • Theoretical　Studies　on　a　Chemically　Reactive　System by　Non－equilibrium　Thermodynamics　I Thermal　Runaway　Reaction
    Akimitsu Ishi and Shukuji Asakura
    1993 Volume 32 Issue 3 Pages 155-159
    Published: June 15, 1993
    Released on J-STAGE: July 31, 2017
    DOIhttps://doi.org/10.18943/safety.32.3_155
    JOURNAL FREE ACCESS
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    The　instability　of　chemically　reactive　systems　is　closely　related　to　potential　hazards,　This　instability　appears　when a　system　is　nonlinear　and　far　from　thermodynamic　equilibriuln, The　stability　of　a　chemica11y　reactive　system　is　analysed　on　the　basis　of　non－equilibrium　thermodynamics　in　this　paper．The　heat　conduction　and　chemical　reactions　are　treated　together　in　terms　of　entropy　production．The　stability　criterion of　a　chemically　reactive　system　is　derived　being　consistent　with　conventional　one．The　present　theory　elucidates　that　the instability　results　from　the　negative　resistivity　of　reaction　rate　to　affinity　inherent　in　a　chemically　reactive　system．

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