In order to investigate the source and chemical composition of precipitation were meased at eight sites in the pusan region during the period from February to September 1995.289 samples of precipitation were collected by automatic seperation sampler of 6-step,and the amount of dissolved components(H+,Na+,K+,NH4+,Ca2+, Mg2+, C1-,SO4-, NO3-)and conductivity were measured by ion chromatography,pH meter and conductivity meter. In this study,the avefage of total 289 samples pH and electric conductivity xvere 5.99 and 70.3μs/cm,and according to average concentrations of components were composed of SO42-,Ca2+,C1-,NH4+,Na+ Mg2+,NO3-,K+ with 221, 159.8,157,99.9,96.2,56.5,50.9 and 24.6μeq/1,respectively, Colltribution of non-seasalts were larger than the seasalt,which has 71.3 % and among the rest 81.3% was neutralized by ammonia and calcium species to acidfy compounds,such as H2SO4 and HNO3 in the procipitation. Especially,source of calcium compounds was estimated from soil,so,it seems that precipitation is neutralized by Ca2+ than NH4+in pusan,korea.
Neural networks have recently become the focus of much attelltiQn,largely because of their wide range of complex and nonlinear problems.This paper presents a new integrated approach using neural networks for diagnosing process failures as an example of amlysis for a nitric acid cooler process.The fault propagation in process is mQdeled by¢ausal relation・ships from the fault tree and its minimal cut sets.The measurement pattems required for training and testing the neural networks were obtained from fault propagation model.The fault diagnostic multi neural network has the hierarchical structure in which the circuit level network and the component le▽el networks.The circuit level network leams malfmc- tions of control loops(feedback and feedforward type control circuits and protective systems).The component level networks leam component failures and disturbances.The measurement pattems relative to malfunctions of control loops are obtained from top structures of fault trees for process.The measurement pattems relative to component failure and disturbances are obtained from a part of the fault trees for the control loops.The circuit level network first can identify malfunctions of control loops by matching the pattem of process data from plant with the pattem of training data which network leamed.Secondly,the component Ievel networks can identify component failures and disturbances which can lead to system malfunctions.