As a result of the accident at the Fukushima Daiichi Nuclear Power Plant, radiocesium (r-Cs) has been detected in Municipal Solid Waste (MSW) incineration ash discharged from some MSW incineration plants in Fukushima Prefecture. It has been suggested that r-Cs in MSW incineration fly ash, in particular, is easily leached if it comes in contact with water. Therefore, the leaching of r-Cs from MSW incineration ash during temporary storage or after its disposal in a landfill at a final disposal site which may result in contamination is viewed as a problem. In Fukushima Prefecture, determining the leaching characteristics of r-Cs from MSW incineration ash and establishing a method to prevent its leaching from the ash are important problems. In this study, samples were collected in summer and winter from incineration plants that discharge MSW incineration ash containing r-Cs. Subsequently, experiments were done to determine their basic properties and the leaching characteristics of r-Cs. Moreover, an additional study was also performed to ascertain the possibility of using clay minerals to prevent the leaching of r-Cs from MSW incineration ash. The results showed that MSW incineration fly ash contains a high content of chlorides, which might influence the leaching of r-Cs. Moreover, mixing clay minerals in proportions from 5% to 20% of the amount of the sample will effectively prevent the leaching of r-Cs from MSW incineration ash.