The atmospheric concentrations of gaseous and particulate Hg (Hg(p)) and the Hg wet deposition flux at Matsue City located in a region facing the Sea of Japan were measured from December 1998 to November 2001. Observations of 14 chemical components (Al, Ca, Cd, Fe, K, Mg, Mn, Na, Pb, Zn, Cl
-, NO
3-, 5SO
42-, NH
4+) and Pb isotope ratios (
207Pb/
206pb,
208Pb/
206Pb) were also conducted to obtain useful information on the sources of atmospheric Hg including long range transport from the Asian continent. The Hg(p) concentration and the Hg wet deposition flux during winter and spring were higher than those during summer. Especially during spring, their increase was accompanied with an increase in atmospheric concentrations and wet deposition fluxes of Al, Fe, non-sea-salt (nss-) Ca and Mn, major components of soil. This suggests the large contribution of the Kosa phenomenon, which frequently occurred during this season. During winter and the Kosa periods, the Pb/Zn concentration ratio and Pb isotope ratios in air and precipitation observed in Matsue were close to those in the Asian continent. Also, the Hg(p) concentrations during thisseason were significantly correlated (P <0.001) with the concentrations of Pb and nss-SO
42-, which are known to be primarily transported from the Asian Continent . In addition, analysis using the enrichment factor of Hg(p) based on elemental composition of crust and the scavenging ratio of Hg between airborne particulate matters and precipitation showed that the large portion of Hg in precipitation during winter originated from Hg(p) but not gaseous Hg. These indicate that during winter in Matsue, long-range transport of Hg(p) from the Asian continent contributes primarily to the Hg wet deposition. In contrast, Hg wet deposition flux during summer is dominated by the precipitation scavenging of gaseous Hg (i.e., Hg
2+) via the oxidation of Hg
0 by O
3 and so on.
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