This paper describes the observed structure of reaction products formed at high temperature on the interface of steel and sand mould and the relationship between this structure and the resulting sand adherence.
A piece of polished steel and a sand mould, set in contact with each other, were subjected to rapid heating. The experiment was carried out under various conditions of heating atmosphere, temperature, kind of sand and its grain size. As a result three types of sand adherence mechanism could be distinguished.
The relationship of the state of steel-sand interface to this mechanism can be summarized as follows.
1) Type 1 is the case of slag infiltrating and adhering to the surface, following the wüstite (FeO) which has been developed on the grain boundary of steel surface before the melting of steel begins. This adherence, though firm, will not occur unless the slag barrier is extremely tenuous or it is slowly cooled. During cooling, in most cases, cracks develop on the interface, causing the barrier to peel off. As a matter of fact, no such adherence will be seen in steel castings.
2) Type 2 is such adherence as observed when the slag barrier surrounded by the molten steel is subjected to contraction stress after melt-down and the strength of fusion or sintering is very large. Practically it is assumed that it takes place in the core and the re-entrants of products.
3) Type 3 is what is called penetration. If Type 1 and 2 are chemical adherence, this may be called physical one. It is caused by the formation of discontinuous slag layers containing sand grains.
The experiment shows that it can sometimes happen despite considerably severe conditions against penetration, i. e. heating under low pressure, large surface tension and contact angle, and a mere 4 cm metal head.
This is due to an unexpectedly huge void formed by discontinuous layers, developing on the interface, of high-concentrated, high-melting slags of SiO
2 or ZrSiO
4 and the large grains of primary crystals grew in these slags. It will not occur when continuous slag layers are formed. To be good for prevention of penetratien, these layers must be thick if they have low melting point and small viscosity.
They might be thin, however, if they have high-melting point and large viscosity.
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