粉体および粉末冶金
Online ISSN : 1880-9014
Print ISSN : 0532-8799
ISSN-L : 0532-8799
35 巻, 1 号
選択された号の論文の6件中1~6を表示しています
  • 真島 一彦, 平田 武彦, 前田 修平, 庄司 啓一郎
    1988 年 35 巻 1 号 p. 1-5
    発行日: 1988/01/25
    公開日: 2009/12/04
    ジャーナル フリー
    Static tensile properties of HIP'ed Ti-Co binary alloys containing 2 wt% or 4wt%Co were studied, and metallographic and fractographic observation were also carried out by scanning electron microscope and X-ray energy dispersion analysis.
    Despite the low level of oxygen content, the HIP'ed specimen using Hunter process sponge fines as titanium source, showed poorer ductility properties than the HIP'ed specimen using hydride-dehidride Kroll process sponge fines of high oxygen content as titanium source, and it was confirmed that the above mentioned ductility degradation was closely related to the existing NaCl in the HIP'ed specimen using Hunter process sponge fines. Brittle fracture was observed in a part of the specimen using Hunter process sponge fines, which is also considered to be due to the above mentioned NaCl existing in the HIP'ed specimen using Hunter process sponge fines.
  • 小原 嗣朗, 立沢 清彦
    1988 年 35 巻 1 号 p. 6-11
    発行日: 1988/01/25
    公開日: 2009/12/04
    ジャーナル フリー
    Mechanical properties of Fe-Ni-P alloys sintered by using atomized iron powder electroless plated with nickel-phosphorus alloy were studied. The sintered alloys with plated powder showed higher tensile strength and larger elongation than those of sintered alloys with mixed powders. The microstructure of the sintered alloys showed a composite structure consisted of two regions. The one is the intergranular region contained smaller iron particles, where nickel content is higher, forming a kind of skeleton in the sintered alloy. The other is the inside region of larger iron particles where iron remains low alloyed after sintering. This composite structure gives the high tensile strength and the large ductility of Fe-Ni-P alloys sintered with plated powder. The relationship between the tensile strength and the content of nickel and phosphorous (in mass%) of sintered Fe-Ni-P alloys with plated powder was represented by the following empirical equation.
    σ=24.2(Ni+10P)+218 [MPa]
  • Shoji Noda, Haruo Doi, Tatsumi Hioki, Jun-ichi Kawamoto, Osami Kamigai ...
    1988 年 35 巻 1 号 p. 12-20
    発行日: 1988/01/25
    公開日: 2009/05/22
    ジャーナル フリー
    Silicon nitride ceramics were implanted with 200 KeV Cr+ ions and then oxidized at temperatures from 1273 to 1473 K in air. The oxidation scales were examined by RBS, XRD and SEM methods. At temperatures up to 1373 K, in the Cr+-implanted ceramics, the implanted Cr atoms were predominantly oxidized to Cr2O3, which resulted in a reduction of the oxidation of Si4N4 to SiO2, and then the diffusion of impurity cations through the grain boundary to the surface oxide (SiO2) was also retarded. For the oxidation at 1473 K, there was little difference in oxidation behavior between the implanted specimen and the unimplanted one. But the preoxidation at 1273 K of the implanted specimen was found to give the implanted specimen a little better resistivity against the oxidation at 1473 K.
  • 林 宏爾, 永塩 久翁, 山川 晃
    1988 年 35 巻 1 号 p. 21-26
    発行日: 1988/01/25
    公開日: 2009/05/22
    ジャーナル フリー
    The Si3N4-(0-24) mol%Y2O3-(0-27) mol%ZrO2-(4.0-4.6) mol%Al2O3 compacts were sintered under 0.5 MPa of nitrogen gas at 2073 K for 7.2 ks. The room temperature mechanical properties such as transverse-rupture strength (σm), fracture toughness (KIC) and hardness (HV) and the microstructure of the compacts were investigated.
    It was found that the compact showed high strength of about 0.7 MPa in the composition range of low Y2O3, low-high ZrO2 or low-medium Y2O3+ZrO2 contents, and it showed low strength of about 0.3-0.5 GPa in the other composition range. The dependences of both KIC and HV on the composition were nearly the same as am. The low values of the mechanical properties in the above composition range could mainly be attributed to the appearance of the soft grain boundary phases such as Y2SiO5, Y20N4Si12O48, etc., and also to the largeness of the domain of those grain boundary phases.
  • 植木 光生, 斉藤 豪, 斉藤 武志, 北村 幸三, 鈴木 寿
    1988 年 35 巻 1 号 p. 27-32
    発行日: 1988/01/25
    公開日: 2009/05/22
    ジャーナル フリー
    Some properties of a TiC-20 vol%TiN-7 vol%Mo2C-8 vol%Ni alloy with addition carbides of TaC, NbC or WC, such as microstructure, mechanical properties in the temperature range from room temperature to 1273 K, resistance to oxidation at 1273 K, cutting performance for SNCM439 steel, etc., were investigated. Among the results obtained, those of the alloy having additional WC were considered to be of great interest. It was noted that, with increasing the amount of additional WC, the carbonitride structure became especially fine, and in spite of the fine structure, high temperature hardness and cutting performance were highly improved. The discussion on the phenomenon was in detail given.
  • 井手 恒幸, 中野 和則, 高木 研一, 渡辺 忠雄
    1988 年 35 巻 1 号 p. 33-39
    発行日: 1988/01/25
    公開日: 2009/12/04
    ジャーナル フリー
    By utilizing the excellent properties of a boride, a new type of sintered hard alloy has been developed. This alloy, categorized as a cermet, is produced by liquid phase sintering and comprises a M2B (M: metal) boride as a hard phase and a ferrous binder phase containing Cr, Ni and other alloying elements.
    In the present investigation, the sintering phenomena of Fe-(4-8) wt%B-(0-30) wt%Cr-0.3 wt%C alloys are studied by means of TG-DTA, dilatometric measurements and x-ray diffractometry. In addition, the mechanical properties of the sintered alloys are discussed.
    The results can be summarized as follows:
    (1) The hard alloy comprises an Fe2B type boride as a hard phase and a ferrous binder phase containing Cr and C. When the hard alloy contains more than 10 wt% Cr, both Fe2B and Cr2B type borides coexist.
    (2) The liquid phase sintering of the alloy is attained by two liquid forming reactions, namely, γ-Fe +Fe3 (B, C)+M23(B, C)6 L1 and γ-Fe+Fe2B L2, the latter reaction occurring in a higher temperature range.
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