Journal of The Surface Finishing Society of Japan
Online ISSN : 1884-3409
Print ISSN : 0915-1869
ISSN-L : 0915-1869
Volume 72, Issue 9
Displaying 1-8 of 8 articles from this issue
Special Feature / New Advances in Electrochemical Measurement Methods
Reviews
Topics
  • -Self-validating Analytical System for Controlling of Electroplating Baths-
    Aleksander Jaworski, Hanna Wikiel, Kazimierz Wikiel, Kazushige UEKAWA, ...
    2021Volume 72Issue 9 Pages 493-497
    Published: September 01, 2021
    Released on J-STAGE: March 01, 2022
    JOURNAL FREE ACCESS
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Research Papers
  • Yutaka ISHIKAWA, Shunsuke SAITO, Shu OIKAWA
    2021Volume 72Issue 9 Pages 499-502
    Published: September 01, 2021
    Released on J-STAGE: September 02, 2021
    JOURNAL FREE ACCESS

    This study examined growth of single-walled carbon nanotubes (SWCNTs) by hot-filament chemical vapor deposition at low temperatures using a double-layer film consisting of iron and cobalt layers as a catalyst. Ethanol was used as the carbon source. At a 350 ℃ growth temperature, few SWCNTs were grown when only cobalt film was used as the catalyst, although SWCNT growth was confirmed when a double-layer film consisting of iron and cobalt layers was used as the catalyst. The optimal combination for use as the catalyst is iron oxide in a layer (thickness before oxidation, 1.2 nm) on the cobalt oxide in a layer (thickness before oxidation, 1.0 nm). By reduction of these films at 400 ℃ for 30 min, followed by CNT growth at 350 ℃ for 30 min, a vertically aligned SWCNT film with 3.2 μm thickness was obtained.

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  • Masatoshi TAKAYAMA, Kotoku INOUE, Mitsuhiro WATANABE
    2021Volume 72Issue 9 Pages 503-507
    Published: September 01, 2021
    Released on J-STAGE: September 02, 2021
    JOURNAL FREE ACCESS

    Glass substrates with through-glass vias (TGVs) are being developed to improve large-volume and high-speed data communications technologies. To use the substrate as a circuit board, it is necessary to apply highly conductive Cu film on the glass substrate and to form uniform Cu film, even inside through holes. However, forming a uniform metal film on high-aspect-ratio through holes is difficult using conventional high-vacuum sputtering. Therefore, we specifically examined the throwing power of low-vacuum sputtering and formed a Cu film inside through holes of the TGV substrate using a wet plating process combined with sputtering. By selecting an appropriate Cu-plating solution and by optimizing Cu-plating conditions and plated film properties, annealing conditions, and an oxide film form method, we achieved 1.0 kN/m adhesion strength for a Cu film formed directly on a glass substrate. Results of our study also suggest the possibility of performing conformal plating on through holes having a 3.75 aspect ratio(0.3 mm glass thickness, φ80 μm opening diameter).

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