In 1915, Mitsui Mining Company started the research on EElectrolytic production of Zinc, but, because of the unfavorable results of the experiments, the project was abandoned in 1919.
Durring 1930-1931, demand for distilled Zinc cooled down and the stock of distilled Zinc accumulated, but on the other hand, Zinc consumers demanded more electrolytic Zinc for fabrication. So, Miike Z.nc Works started the research on electrolytic production of pure Zinc with Kamioka Cocentrate. Some engineers of Mitsui Mining Company including the author inspected American and Canadian Zinc plants and the project to construct flash roasting plant and electrolytic Zinc plant according to the Trail and Tainton practice respectivly. Des'gncd capacity of the electrolytic Zinc pant has been 6, 000 tons of electrolytic Zinc per year. Mitsui Mining Company made a contract with Consolidated Smelting and Refining Company, B. C. for the application of the patent.
The whole plant was completed in September, 1936.
A Lurgi type multiple-hearth furnace was converted to flash roasting furnace and ball mill, air separator, are injector, waste-heat boiler and other necessary accessories were insatalled.
Advantages of flash roasting are:
1. Low sulphur content in calcine.
2. High concen ration of SO
2 in exit gas, correspondingly high extraction in H
2SO
4 mailing, and, therefore, possibility of mixing S0
2-poor D. L. gas with flash roaster gas.
3. No external heat is needed.
4. Utilization of waste heat as steam piped to electrolytic Zinc plant.
5. If Wedge-type roaster is available, it can be reconstructed easily, and, correspondingly, erection-capital is small.
6. Cost of operation is cheapest among various roasting processes.
Disadvantages of flash roasting are.
1. About 40% of charged are or 50% of calcine shows high sulphur which is not adequate to be used in distillation or electrolytic plant.
2. Repair cost of machines is comparatively high.
3. Electric power cost is comparatively high.
But advantages are more than enough to cancel disadvantages.
According to Mr. Tainton's findings, high acid-high current density process has been applied in electrolytic Zinc plant.
Batch leaching, Burt filter and two stage purification are carried out.
Electrolyte is composed of H
2SO
4 19-20%, Zn 6-7%
Temperature of elecirolyte is kept between 40-50°C.
Current density is 750-800 amps/m
2.
Cathod deposits are stripped every 16 hours.
Electric power consumption is between 3, 800-4, 200K. W. H./T
Stripped deposits are melted with Ajax-Wyatt Low frequency indgetion furnace.
Parity of electrolytic Zinc Slab is 99.97-99.988%
First purification residue is treated for copper and cobalt.
Second purification residue is roasted and leached with H
2SO
4 and Cd-sponge is precipitated from the pregnant solution, purified and electrodeposited with insoluble anode electrolysis.
Purity or electrolytic Cadmium is around 99.98-99.99%.
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