Reflectivity spectrum of YIG was measured at room temperature in the Y
3+, 4p core excitation region. The optical constants are obtained by a multi-angle method. Two broad spectral bands at 29.3 and 33.3, eV and five small structures at 20.2, 22.5, 27.3, 36.5 and 40, eV were newly found in ε
2 spectrum. The spectral structures are assigned; the large spectral band at 33.3, eV is made up of two transitions from Y, 4p
6 1S
0 to Y, 4p
5, 5s
1 (3/2, , 1/2), (1/2, , 1/2), where the first member in the parenthesis indicates the total angular momentum j of hole and second specifies j of electron, the structure 29.3, eV is made of a transition to Y, 4p
5, 4d
1 1P
1. In YIG the energy positions of Y, 4p
5, 5s
1 (3/2, , 1/2), (1/2, , 1/2) are about same in Y
3+ free ion, but Y, 4p
5, 4d
1 1P
1 is shifted by 5.7, eV.
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