The molecular nitrogen ion, N
2+, and singly and doubly charged atomic nitrogen N
+, N
2+ were formed by laser multiphoton ionization and detected in the time-of-flight (TOF) spectra. The excitation lasers were a Ti: sapphire femtosecond laser (up to 1.0×10
16 W/cm
2 in 100 fs at a wavelength of 790 nm) and a nanosecond laser (up to 1.2×10
13 W/cm
2 in 9 ns at 532 nm). The highest signal intensity among these ions resulted from N
2+ in the major region of the laser fluence.
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