Fabrication of dimension-controllable nano/mesoscopic architectures is an important challenge in nanoscience and nanotechnology, since it can exploit the advantageous intrinsic optoelectronic properties of π-conjugated systems in their molecular building blocks. Supramolecular method that is being utilized in my research is controlling the architecture and dimensionality of hierarchical fullerene (C
60) nanostructures by varying the nature of the solvent system, this approach induces “Fullerene Polymorphism”. Flower-like fractal superstructures are obtained in the study and they show superhydrophobic property at the surface. Other focus is development of new fluid nanocarbons such as semi-conducting liquid crystalline-C
60 and room temperature liquid-C
60. The liquid-C
60 is a single component nanocarbon material with high fluidity and shows the potential use in practical materials. A delicate balance of the intermolecular interactions leads to a wide variety of supramolecular morphology and this understanding of the hierarchical assembled systems should inspire further studies for self-organized supramolecular chemistry, nanocarbon science, bio-mimetic structures, nanotechnology as well as materials science.
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