The soft matter such as polymers, surfactants, and colloidal particles forms a variety of ordered structures as a result of a delicate balance of energetic interactions and entropic interactions originated from the large internal degree of freedom. Recently complex systems consisting of surfactant and polymer acquire great interests because they play important roles in the field of biology, medicine, cosmetic, and food industry. In this review we introduce recent researches on the complex systems from the soft matter physics point of view. We deal with two cases, one is that polymers are introduced between lamellar bilayers of surfactant/water systems, and the other is that polymers are confined in the spherical microemulsion droplet in water/surfactant/oil ternary systems. In the case of lamellar + polymer systems, added polymers bring attractive inter-lamellar interaction due to the decrease of the conformation entropy and the depletion effect. Whereas, in the case of microemulsion + polymer systems, the confined polymers induce unique multi-stage morphology transitions as a result of a delicate balance of confining entropy of polymer chain and elastic energy of surfactant membrane. We believe that the surfactant membrane and polymer complex systems involve quite fruitful soft matter physics, which is useful to understand a variety of biological and industrial phenomena.
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