Lysophospholipids (LPL) are present in most of starch granules of cereal grains, and formed complex with starch in the granules. The starch complexing abilities of lysophospholipids, monoacylglycerols and fatty acids contained in the starch were found to be independent of the straightchain structure and the steric hindrance by double bonds in fatty acids. The different starch complexing abilities for monoacylglycerols consisting of unsaturated fatty acids such as oleic acid or linoleic acid were reported. The starch complexing abilities of polyhydric alcohol monoesters consisting of unsaturated fatty acids were found to be similar to the abilities of the esters consisting of saturated fatty acids, and depend greatly on the dispersion methods, and then related to their micelle forming properties in the solution. In this review, studies of the starch complexing abilities of LPL contained in the starch, next, the minimum degrees of polymerization of amylose requiring for complex formation of monoacylglycerols and LPL, furthermore, the rheological properties of wheat starch gel blended with LPL and the application in food, were described.
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