On the basis of non-steady gas diffusion theory, a portable apparatus was constructed to measure CO
2 diffusion coefficient of snow.It consists of a CO
2 supply chamber with an electrode CO
2 meter, a snow sample tube to be connected with the chamber and gas-supply equipment. After replacing the air in the chamber with CO
2 with known concentration, the temporal change of CO
2 concentration in the chamber was measured.Diffusion coefficients were calculated from the rate of concentration change and information of system geometry.
To examine the reliability of the apparatus, diffusion coefficient of CO
2 in glass beads and straight glass tube bundles of known geometry were measured.Obtained values showed close agreement with expected values. Reproducibility was excellent, giving relative variation of measurements less than 5%.CO
2 diffusion coefficients of newly fallen snow, granular snow and compacted snow, densities ranging between 0.10 and 0.55g/cm
3, were measured.Measured values were between 0.40 and 0.89cm
2/s (at0°C) and were proportional to the porosity of snow.The apparatus proved to be useful for field measurements.
View full abstract