In order to reconstruct the past climate and environmental changes, we carried out sampling and chemical analyses of surface snow and ice, and precipitation on Qiyi Glacier, Qilian Mountains, western China, in August and September 2004. A mean pH value of surface snow and ice was 7.07. We found high correlation (r=0.98) between difference of total cations concentration and total anions concentration (ΔC) and Ca
2++Mg
2+ concentrations. It was indicated that these sources were carbonate mineral such as CaCO3 in soil and loess and these species influenced pH of surface snow and ice of the glacier. The chemical composition of Qiyi Glacier was similar to that of glaciers of the Tien Shan, suggesting that that of the glacier was strongly affected from aeolian dust from arid/semi-arid regions. It was suggested that a source
of Na
+ and Cl
− in surface snow and ice was mainly rock salt (halite) at the glacier, because both species had high correlation (r=0.93) and mean of Na
+/Cl
− ratio was almost 1.00. Ratios of Ca
2+,Mg
2+ and ΔC to total ionic concentrations were predominant in surface snow and ice and precipitation and greater in ice and snow than in precipitation at the glacier. It was suggested that these were influenced by dissolution of dust with melt-freeze processes and dry deposition. The sources of chemical species except NH4
+ in the samples were estimated such as soil and dust, anthropogenic and rock salt based on the results of the principal component analysis (PCA).
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