NIPPON GOMU KYOKAISHI
Print ISSN : 0029-022X
Volume 53, Issue 3
Displaying 1-8 of 8 articles from this issue
  • [in Japanese]
    1980 Volume 53 Issue 3 Pages 129-145
    Published: 1980
    Released on J-STAGE: April 16, 2008
    JOURNAL FREE ACCESS
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  • [in Japanese], [in Japanese]
    1980 Volume 53 Issue 3 Pages 146-157
    Published: 1980
    Released on J-STAGE: April 16, 2008
    JOURNAL FREE ACCESS
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  • [in Japanese]
    1980 Volume 53 Issue 3 Pages 158-161
    Published: 1980
    Released on J-STAGE: April 16, 2008
    JOURNAL FREE ACCESS
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  • [in Japanese]
    1980 Volume 53 Issue 3 Pages 162-169
    Published: 1980
    Released on J-STAGE: April 16, 2008
    JOURNAL FREE ACCESS
    Download PDF (557K)
  • [in Japanese]
    1980 Volume 53 Issue 3 Pages 170-176
    Published: 1980
    Released on J-STAGE: April 16, 2008
    JOURNAL FREE ACCESS
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  • Crosslinking of Chlorine-Containing Elastomers by Sulfone-Ether Diamine Oligomers
    Shinji INAGAKI, Yukio ONOUCHI, Hiroshi OKAMOTO, Junji FURUKAWA
    1980 Volume 53 Issue 3 Pages 177-181
    Published: 1980
    Released on J-STAGE: April 16, 2008
    JOURNAL FREE ACCESS
    Sulfone-ether-diamine oligomers (SED oligomers) were prepared by the condensation of p-aminophenol, bisphenol A and dichlorodiphenyl sulfone. The oligomers were mixed with chlorine-containing elastomers, such as chlorinated polyethylene (CPE), chloroprene rubber (CR), epichlorohydrine rubber (CHR) and epichlorohydrine-ethylene oxide rubber (CHC), and the physical properties of their vulcanizates were examined.
    As the result, it was found that the tensile properties and heat resistance of vulcanizates were improved by the compounding of SED oligomers. Through an increased crosslink density of the vulcanizates, the SED oligomers may be estimated to contribute to the crosslinking reaction.
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  • COMPARISON OF THE DISPERSION PARTICK WITH THE AGGREGATES OF XONOTLITE ON THE MECHANICAI PROPERTIES OF THE PVC-XONOTLITE MIXTURE SYSTEM
    Isao SOUMA, Takashi YOSHIMURA, Hiromutsu WAKANO
    1980 Volume 53 Issue 3 Pages 182-187
    Published: 1980
    Released on J-STAGE: April 16, 2008
    JOURNAL FREE ACCESS
    The filler effects of the dispersion particle of Xonotlite on the mechanical properties of PVC-Xonotlite mixture system were compared with those of the aggregates. Usually, powder of Xonotlite is obtained as aggregates of the needle crystal, while it is hard to make dispersion particle from the aggregates by ordinary mill such as a grinding or ball mill. Therefore, the dispersion particle in this study was prepared by two kinds of procedures. Namely, the one was an application of jet air to the aggregates, the other was an addition of hexa methyl di-siloxane(HMD S) to the reaction system to retard aggregation when Xonotlite was synthesized. The dispersion particle obtained in this manners was impregnated into PVC by mixing roll.
    An increase in tensile strength and elongation was observed on these samples compared with the sample filled with the aggregates, but Young′s modulus in the bending test and dynamic modulus (E′) decreased. And a rise of glass temperature (Tg) was smaller than that of the aggregates. From these results, it may be presumed that (1) a surface interaction between particle and matrix decreased because the complicated surface structure of the aggregates was simplified. (2) a volume fraction of the particle in the matrix decreased because of the disintegration of aggregates. (3) a dispersion character of the particle became good, and faults in the matrix decreased; and (4) HMDS affected chemically a further decrease of the surface interaction.
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  • [in Japanese]
    1980 Volume 53 Issue 3 Pages 188-189
    Published: 1980
    Released on J-STAGE: April 16, 2008
    JOURNAL RESTRICTED ACCESS
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