Hydrogen isotopes transport properties of first wall candidate materials, both metallicand ceramic, have been widely investigated. In the case of such metals as nickel, vanadium orstainless steel, the observed hydrogen permeation behaviors can be intimately correlated withthe surface impurity compositions. The impurities such as sulfur and oxygen were found tosignificantly reduce hydrogen recombination rate at the surface. On the other hand, as forgraphite and other carbon materials, the hydrogen permeation rate depends on the porestructure, namely, the pore size and its distribution, as well as the tortuosity.
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