Tropospheric air samples were collected aboard an aircraft up to an altitude of 7km. Vertical and horizontal distributions of tropospheric methane (CH
4) over Japan were measured using a gas-chromatograph equipped with a flame ionization detector.
CH
4 mixing ratios in vertical and latitudinal profiles varied widely. The CH
4 mixing ratio was high when the air from the mid-to-high latitudes of the Asian continent source region of CH
4 was sampled. The CH
4 mixing ratio was highest in air from Siberia and rather low in air from China. When this air mixed with air from the stratosphere—very clear from the high O
3 mixing ratio—the effect on the CH
4 mixing ratio was not clear because CH
4 is photochemically stable and does not apparently decrease from the upper troposphere to the lower stratosphere. When the aircraft went directly across tropopause folding, however, very high O
3 and low CH
4 mixing ratios were observed. The distance of transport from the intrusion region would be an important factor for both O
3 and CH
4 mixing ratios. Low CH
4 mixing ratio was observed when the air was sampled in maritime air mass because they were not affected by Asian continental sources.
Between February 1986 and February 1992, mean CH
4 mixing ratios over Japan (25-44°N, 124-144°E) steadily increased. Using data between November and February, we obtained an average annual increase of 12.0±7.0 (confidence interval: 70%) ppbv/year using a linear least square fit. From February 1992 to December 1993, the mean volume mixing ratio decreased slightly. The overall annual increase from February 1986 to February 1996 was 9.6±4.9 ppbv/year. These results indicate that the increase was larger in the mid-1980s than in the 1990s and has been declining.
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