Recently, it has been confirmed that ozone in room air actively generates various free radicals by reacting with the organic and inorganic compounds existing in the air. The free radicals and other products of chemical reactions are often more irritating than their precursors. In particular, the products of ozone/terpenes reactions cause greater airway irritation in mice than would be predicted based on the known response of mice to ozone or terpenes. Such chemical reactions can significantly alter the concentrations of indoor pollutants. Furthermore, heterogeneous reactions between ozone and various surfaces occur, which further reduce the ozone concentration and must be considered in the ozone balance of indoor environments. Weschler and Shields (2000) have simulated chemical reactions in indoor air using mass balance models and assuming perfect mixing; these simulations examined the influence of ventilation rates on uni- and bimolecular reactions. Using computational fluid dynamic (CFD) simulations, Sorensen and Weschler (2002) have reported the distribution of chemical compounds resulting from various indoor chemical reactions. However, there is insufficient data to experimentally verify the two-dimensional or three-dimensional distributions resulting from chemical reactions in indoor air. Here, we isolate the surface reactions and measure the distribution of ozone within a 2D model room. The analyzed room model had one supply inlet and one exhaust outlet, with a cavity of dimensions 1.5m(x)×0.3m(y)×1.0m(z) in which a two-dimensional flow field was developed. A clear re-circulating flow was observed in the room generated by the forced ventilation. In order to discuss the order of chemical reactions or wall surface deposition for ozone, the concentration distributions of ozone in the model room were measured for various building materials. CFD analysis corresponding to the experimental conditions and with a built-in ozone wall surface deposition model was carried out. The results of CFD prediction were in good agreement with the room model experiment.
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