Galvanic corrosion of aluminum alloy castings, composed of 99.8% Al, Al-5% Cu, Al-4% Si-4% Cu, Al-11% Si, Al-7% Si-6% Cu, and Al-5% Mg, was investigated in contact with 18-8 stainless steel, mild steel, and copper in 5% NaCl aqueous solution at 35°C and at boiling point under ordinary atmospheric pressure. corrosion behaviors of these alloys at boiling point were quite different from those at 35°C. The increasing order of corrosion rate of the aluminum alloys at 35°C was arranged as follows.
Al-5% Mg=99.8Al<-11% Si<Al-7% Si-6% Cu
However, the above order was observed inversely at boiling point.
Al-5% Mg was most strongly attacked among these alloys when it was coupled with the stainless steel at boiling point. High corrosion rate of this alloy was attributed to Mg(OH)
2 formed in the solution, because of its basicity. The corrosion rate of aluminum would be high under this condition. Al-7% Si-6% Cu was least corroded; in particular, very little galvanic effect was observed when it was coupled with mild steel.
The gravimetric loss of weight on galvanic corrosion of pure aluminum was about three times as large as that calculated from the current flowing through the galvanic couple.
Maximum galvanic current was observed at about 75°C in the couple of pure Al-mild steel or pure Al-copper. However, extraordinary large galvanic current was observed in the couple of pure Al-stainless steel.
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