Electrical resistivity of Mg-Al binary alloys containing up to 14.2%Al has been measured at 77K and 300K. Resistivity of alloys containing up to 9.69%Al, which give perfect solid solution after appropriate solution treatments, shows a good linear relation with a function g(
X) =
X (1-2.86
X) of aluminium atomic fraction
X deduced by an empirical correction of Nordheim's rule. The resistivity at 300K and 77K can be expressed as,
44<ρ
Mg-Al300/nΩm=_??_1.966×10
3X(1-2.86
X)+44.73_??_± 1.2<175
5<ρ
Mg-Al77/nΩm=_??_2.095×10
3X(1-2.86
X)+5.46_??_± 1.0<142.
From gradients Δρ
g(X) of these linear relations, η
Mg = Δρ
300/Δρ
77 is determined to be 0.938 and the deviation from Matthiessen's rule (DMR) is negative in agreement with previous reports on alloys up to 2.8%Al. Relation between R = ρ
300/ρ
77 and ρ
77 corrected with the DMR is obtained as
5<ρ
Mg-Al77/nΩm=_??_39.53/(R-0.938)+0.175_??_± 1.0<142
for change in concentration of solute aluminium in Mg-Al solid solution.
dρ/d
T measured between 280K and 308K decreases with aluminum concentration, which also coincides with the negative DMR of solute aluminum. The
R of two (α + β) phase specimens shows a tendency to increase with volume fraction of β (Mg
17Al
12) phase.
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