The specific electrical conductivity of the molten salts of sodium fluoride-calcium fluoride-barium fluoride-aluminum fluoride was measured.
(1) The specific electrical conductivity of the NaF-AlF
3 binary molten salts was 5.17 to 2.33ohm
-1cm
-1 up to the concentration of 50wt% of AlF
3 at 1000°C and agreed fairly well with the values reported in other works.
(2) When the concentrations of CaF
2 and BaF
2 were 5 to 20wt% and 30 to 50wt%, respectively, the electrical conductivity of the quaternary system was 4.13 to 0.73ohm
-1cm
-1 at 950°C.
(3) If the concentration of both CaF
2 and BaF
2 was constant, the electrical conductivity decreased almost linearly with an increase of AlF
3. An increase of CaF
2 and BaF
2 also decreased the conductivity.
(4) In the quaternary system, such compounds as Na
3AlF
6, NaAlF
4, Na
5Al
3F
14, NaCaAlF
6, NaBaAlF
6, CaAlF
5 and BaAlF
5 were formed and sevearl complex ions such as AlF
63- and AlF
4- etc. were considered to exist. The structures of the molten salt were not clearly known. The validity of the additivity law in the electrical conductivity by each component was questioned.
(5) The specific electrical conductivities of Hurter's and Sumitomo's bath at 750 to 950°C were 0.96 to 1.25ohm
-1cm
-1 and 0.87 to 1.10ohm
-1cm
-1.
(6) It appears that some other compositions of the quaternary system can be used as an electrolyte of aluminum refining, besides Hurter's and Sumitomo's bath.
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