Journal of the Society of Powder Technology, Japan
Online ISSN : 1883-7239
Print ISSN : 0386-6157
ISSN-L : 0386-6157
Volume 31, Issue 11
Displaying 1-8 of 8 articles from this issue
  • Kunihisa OSASA, Yuushi YAMAGATA, Toshitaka OMORI
    1994Volume 31Issue 11 Pages 778-782
    Published: November 10, 1994
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
    The adsorption of the polybutadiene terminated with a polar group on hydrophilic zeolite particles and the resulting dispersion stability were examined in non-aqueous solvents with a different solubility parameter. The amount adsorbed of the polymer with group terminations was considerably larger than that of the homopolymer. With increasing the polarity of group terminations, the amount adsorbed increased, and dispersion stability improved. For a polymer with the same polarity, the amount adsorbed was independent of the solubility parameter of the solvents. The stability effect was eluciated by the steric stabilization theory on the basis of the polymer conformation on the particles's surface.
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  • Munetake SATOH, Naoyuki KONDO, Tomohiro IWASAKI, Kei MIYANAMI, Yuzo OK ...
    1994Volume 31Issue 11 Pages 783-788
    Published: November 10, 1994
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
    A rotary type of rheometer with a conical rotor has been applied to measure the flow characteristics of powders. The shearing torque as a function of the boundary area in the friction zone of the rotor was continuously measured during intrusion of the conical rotor into the powder bed.
    The effects of the rotor shape and operating conditions on the torque variation curves were investigated, and an empirical coefficient C including factors of stress and internal friction coefficient was proposed to express the change in the physical properties of the powders.
    The applicability of this testing method was confirmed by measuring two typical powder samples: a binary-component mixture of fine powders processed under different operating conditions, and polymer particles coated with different kinds of wax.
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  • Munetake SATOH, Tatsumori YOSHIDA, Kei MIYANAMI, Yuzo OKUDAIRA
    1994Volume 31Issue 11 Pages 789-794
    Published: November 10, 1994
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
    A new type of powder mixer has been developed for preparing highly homogenized mixtures and composites of various particulate materials. It consists of a horizontally rotation (at low speed) elliptical barrel and an elliptical impeller (rotating at high speed) installed coaxially inside the barrel. A strong shear force acts on the powders periodically at the narrow clearance between the barrel and the rotor tip.
    The effects of the operating conditions on the degree of mixing and dispersing have been investigated by using an optical method. The applicability of this equipment to the manufacturing of a variety of powder composites has been shown.
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  • Takashi OGIHARA, Teruaki YANAGAWA, Nobuo OGATA, Koukichi YOSHIDA, Mabi ...
    1994Volume 31Issue 11 Pages 795-802
    Published: November 10, 1994
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
    Monodispersed, spherical MTiO3(M=Ba, Sr, Pb) fine powders were synthesized by the hydrolysis of metal alkoxide in a mixture of alcohol and dipolar aprotic solvent. Ba-Ti, Sr-Ti or Pb-Ti double alkoxide were used as starting materials. The synthesis factor such as water and alkoxide concentration, type of solvent and reaction temperature influenced particle size, particle size distribution and the state of aggregation. Monodispersed powders were obtained when the volume ratio of octanol to acetonitrile was in the range from 60:40 to 80:20. As-prepared powders were amorphous and then crystallized to a perovskite-type structure by calcination at 600°C. Spherical morphology was retained after calcination at 600°C. Fluoresence X-ray analysis showed that the BaO/TiO2, SrO/TiO2 and PbO/TiO2 ratio of as-prepared powders was 48:52, 49:51 and 49:51, respectively.
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  • Toshihiro ISHIMORI, Mamoru SENNA
    1994Volume 31Issue 11 Pages 803-807
    Published: November 10, 1994
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
    The delamination of talc platelets was carried out by two different wet grinding methods, i. e., by a ball mill, and by a rod mill. The rate of rotation, grinding time and volume of suspension were systematically varied. The best talc platelets with a maximum aspect ratio of 42 were obtained when suspension with the solid volume fraction of 0.15 was filled to a volume of 25% of the capacity and rotated at 77rpm in a ball mill. The change in the pH of the suspension and mechanical amorphization were also observed indicating simultaneous mechanical activation.
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  • Isao SEKIGUCHI
    1994Volume 31Issue 11 Pages 808-817
    Published: November 10, 1994
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
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  • Yusuke SUZUKI
    1994Volume 31Issue 11 Pages 821-823
    Published: November 10, 1994
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
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  • 1994Volume 31Issue 11 Pages 824-827
    Published: November 10, 1994
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
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