Na-A zeolite was synthesized from diatomaceous earth (DE) of Si source. Pretreatment of DE with NaOH solution at 85°C for 24h was conducted to dissolve Si
4+ from the amorphous phase of DE to form zeolite P. After the pretreatment, the molar ratio SiO
2/Al
2O
3 of the solution was adjusted from 0.7 to 4.0 by adding NaAlO
2 solution and aged at 85°C for 24h. The Na-A zeolite was formed at SiO
2/Al
2O
3=0.7-1.3, although the materials were brown in color being a mixture with residual DE. In order to obtain a single phase Na-A zeolite, DE and NaOH solution added into the tube made by semipermeable membrane were pretreated in the same NaOH solution at 85°C for 24h. After the pretreatment, the tube was removed and the molar ratio SiO
2/Al
2O
3 of solution was adjusted from 0.7 to 4.0. The precipitates formed from the solution were aged at 85°C for 24h. After the aging, white precipitates were obtained over the whole SiO
2/Al
2O
3 ratio. At SiO
2/Al
2O
3=1.3, the materials formed were identified as a single phase Na-A zeolite.
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