Pyrolysis process of woody biomass was modeled by adopting two-step ractions, that is, the parallel reactions producing gases, tar and char from the biomass, and the subsequent reactions generating gases and char from the tar. The pyrolysis experiments of woody biomass for the particles with a mean diameter between 1.1mm and 11mm showed that the change of average temperature in the biomass layer with time can be divided into four regions. Generated gas flow rate exhibited two peaks when the heat flow rate was in endothermic regions. Therefore, the heterogeneous chemical reactions through the pyrolysis should be modeled by four-step processes; i. e., i) evaporation of water, ii) decomposition of cellulose, iii) decomposition of generated tar and iv) decomposition of generated char. Among them, the decomposition of cellulose, which generates tar and char, are strongly affected by the water contents of biomass.
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