In a series of studies on fabrication of thick-film inorganic electroluminescence device by co-firing of multi-layers consisted of phosphor, dielectric materials, transparent electrode and back electrode, effects of calcination condition, microstructure changes of Ca
0.997Pr
0.002TiO
3 films during calcination or sintering, and barium diffusion from dielectric material to (Ca
1-xSr
x)
0.997Pr
0.002TiO
3 phosphor on the photoluminescence characteristics were investigated. The results showed that calcination temperature above 800°C was necessary for the phosphor to suppress the crack and delamination caused by gas evolution and expansion during co-firing. The sintered films with dense and high crystallinity could be prepared by two steps heat treatment consisted of calcination and co-firing. It was also shown that chemical composition change and solid solution formation due to the barium diffusion to the phosphor during co-firing affected remarkably on the photoluminescence intensity. The combination of CaTiO
3:Pr phosphor and BaTiO
3 dielectric material was an appropriate system for the co-firing of thick films because of no barium diffusion and formation of solid solution. It was demonstrated that the inorganic electroluminescence device could be prepared with dense and high crystalline films by selecting the combination of phosphor and dielectric materials and controlling their calcination and sintering conditions.
View full abstract