When a fiber assembly such as cloth or yarn is washed, a chemical to be washed off from fiber assembly migrates in fiber phase and also water phase in a fiber assembly and subsequently transfers to water.
In such processes the diffusion coefficient of a chemical agent in a fiber differs largely from that in water. These processes were analyzed on the basis of a diffusion theory. Assuming that a single fiber is a column and a fiber assembly is a column or a plane, the following theoretical relations, representing residual fraction of a chemical agent in a fiber assembly during washing, were obtained :
y(t) =(∞Σi=1)(∞Σj=1)A
ijexp (-D
fμ
ij2/R
2t)
where, t; washingtime (s)
y(t); residual fraction of a chemical in a fiberassembly
D
f; diffusion coefficient of a chemical in a fiber (cm
2/s)
R; radiusoffiber (cm)
A
ij= (2Q
i/ (1+α) β
2μ
ij2)
21/1+α/1+αJ
12 (μ
ij) /J
02 (μ
ij) (column)
A
ij=1/2 (2Q
i/ (1+α) β
2μ
ij2)
21+α/1+αJ
12 (μ
ij) /J
02 (μ
ij) (plane)
Q
i;roots J
0 (Q
i) =0(column)
roots of cos (Q
i) =0 (plane)
μ
ij;roots of Q
i=βμ
ij√1+α2J
1 (μ
ij) /μ
ijJ
0 (μ
ij)
J
0, J
1 : Bessel functions of order 0 and 1
α, β : constants depending on a diffusion coefficient of a chemical in a fiber and water, geometrical characteristics of a fiber assembly and so on.
The theoretical results calculated by using the above equations agree closely with the experimental values and also very closely with the results obtained using the simplified equation on which we had previously reported.
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