Although metal soaps have little solubility in water, they are soluble in aqueous solution of surface active agent in some extent. To make the most of this fact, surface active properties of several metal (Li, Mg, Ca, Ba and Na, K- reference substances) soaps in water were investigated.
When an alkaline earth metal soap is added to the aqueous solution of dodecyl pyridinium chloride (DPC), it dissolves without causing precipitation or becoming cloudy, to the extent of about 1/3 molar ratio of metal soap to DPC. Especially ricinoleates show high solubilities.
A remarkable synergistic effect was observed for the values of surface tension of the mixed solutions.In all cases the molar ratios of the metal soap to DPC range were from about 1/3 to 1/10 aprox., and when the concentration of the metal soap was about 1×10-5 to 1×10-2mole/l except the concentration of DPC was over 2×10-2 mole/l approx. in the mixed solution, the equilibria or minimum values of surface tension were observed. Laurates were the most excellent values and lowered to 25 dynes/cm, ricinoleates also lowe red to 31 dynes/cm. Although there were no great differences with respect to kinds of the metals, barium salts showed better result.
The inclinations of the contact angle of the mixed solutions against the chromium plate were very similler to that of surface tension depression with the variations of mole ratios, kinds of fatty acid residues and metals, the ranges of effective concentration and with remarkable synergistic effects. Barium laurate solution showed about 10° angle.
In case of electric conductivity of the mixed solution, the rate of increase in specific conductance decreased with increase in the concentration, and the breaking point (CMC) in the curve of specific conductance against the concentration which usually seen in the single system were not observed, in either cases molar atio of DPC to metal soap was fixed or varied. Alcaline earth metal-salts, especially ricinoleates, showed high values.
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