The influence of surface oxide films on anodic oxidation process in an organic electrolyte was investigated from the perspective of the breakdown voltage (
Ebd). Composites of anodic oxide films were analyzed using X-ray photoelectron spectroscopy (XPS). Pre-oxidized anodic oxide film at 15 V drastically increased
Ebd from 26 V to 63 V in organic electrolyte (1M LiBF
4/ethylene carbonate : diethyl carbonate (1 : 1 v/v%)). Furthermore, XPS analysis of the anodic oxide film structure revealed AlF
3/AlO
x/2F
3−x/Al. The rise in
Ebd would be explained by the change in the unevenness of anodic oxide film.
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