粉体工学会誌
Online ISSN : 1883-7239
Print ISSN : 0386-6157
ISSN-L : 0386-6157
60 巻, 8 号
選択された号の論文の7件中1~7を表示しています
論文
  • 横山 公一, 佐々木 郷紀, 清澤 正志, 佐藤 一教, 平野 知之, 荻 崇
    原稿種別: 論文
    2023 年 60 巻 8 号 p. 462-469
    発行日: 2023/08/10
    公開日: 2023/11/03
    ジャーナル フリー

    CO2 methanation is a technology that produce CH4 using CO2 and H2 as raw materials through the Sabatier reaction. In the present study, the effects of temperature characteristics and CO2 conversions in the two types of catalyst reactors (i.e., granular catalyst reactor, catalyst coated reactor) were evaluated. For the catalyst coated reactor, the base substrate was formed to a circular tube composed of agglomerates of metal particles by the Additive Manufacturing method. The catalyst layer was produced by the slurry coating method. The fine particles in the slurry were obtained by pulverizing the commercially catalyst with a hammer mill. The thickness of the catalytic particle layer was increased by multiple coating process, and the catalyst base-substrate was not exposed. The temperature rise of nearly 50°C occurred in the granular catalyst reactor at a set temperature of 300°C, while in the coated catalyst reactor the temperature was almost flat along the gas flow direction. Furthermore, it was clarified that the CO2 conversions were determined by the maximum temperatures of the catalyst reactors. The proposed reactor in this study showed the possibility for solving the problem in the methanation process that is the temperature rises during the reaction.

  • 塩入 一希, 大村 浩之, 浅井 光輝, 三目 直登
    原稿種別: 論文
    2023 年 60 巻 8 号 p. 470-480
    発行日: 2023/08/10
    公開日: 2023/11/03
    ジャーナル フリー

    It is important to consider the equipment wear in bead mills to maintain quality and control operational costs. In the conventional wear simulation, mesh deformation is applied using wear laws. There is a problem that the mesh is broken when large mesh deformations occur. We propose the wear simulation model which represents shape deformation by the interface capturing method in this study. The proposed model is robust because the model deforms equipment shape without requiring mesh deformation. Moreover, proposed model reduces computational costs by coupling with IB-DEM (Impulse-Based Discrete Element Method) which allows for a larger time step size than conventional DEM. We demonstrate the wear results when significant shape deformations occur due to collision with beads. We verify the proposed model by comparing the numerical results with actual worn parts by applying to the dry bead mill.

解説 SDGs シリーズ
解説 フロンティア研究シリーズ
  • 伊與木 健太
    原稿種別: 解説 フロンティア研究シリーズ
    2023 年 60 巻 8 号 p. 485-488
    発行日: 2023/08/10
    公開日: 2023/11/03
    ジャーナル 認証あり

    The successful application of zeolites in diverse fields largely relies on their high stability, unique catalytic activity, and adsorptive properties. However, the property requirements for zeolites have become severe due to their diverse and demanding applications. Novel post-synthetic treatment of zeolites show that properties of zeolites can be tuned by simple liquid-mediated treatments, in which new concepts such as pore-filler stabilization and pore-opening migration have been proposed. For example, development of extremely stable zeolites that can withstand over 1000°C steaming and dealumination of small-pore zeolites, which had been believed to be impossible, were reported and further superior zeolite-based catalysts with longer catalytic life and/or improved selectivity have been realized.

新・基礎粉体工学講座
feedback
Top