The solutions containing predicted salts obtained from univalent permselective cation and anion exchange membranes were evaporated to given stages at boiling point (1 atm.) and equilibrated at 70, 45 and 25°C respectively, for the purpose of the studies on the elevation of specific gravity, the change of the composition and the deposition of salts.
The results obtained were as follows:
1) After 700g water per 1 kg brine was evaporated, both boiling point and specific gravity increased sharply. Magnesium chloride seemed to have the most influence on the boiling point elevation and increase of the specific gravity. Between the latter two and chlorinity, linear relations were recognized, which can be used for the index of evaporation in the actual salt-factories.
2) Amount of deposited salts increased linearly with that of evaporated water. The more water was evaporated, the less temperature affected the amount of deposited salts.
3) Calcium sulfate precipitated in about same concentration as sodium chloride. If brine contains 0.1% calcium sulfate, it was deposited after deposition of sodium chloride. Thus, it will hardly affect the heat transfer as scale.
4) Potassium chloride was deposited in more advanced range of concentration than sodium chloride or calcium sulfate, that is, after 95% deposition of sodium chloride was at 25°C. It may be said, therefore, that there seems to be no fear of contamination of sodium chloride with potassium chloride in the usual salt makings.
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