We have proposed a novel micro-calorimetric hydrogen sensor based on the temperature difference detection due to the exothermic reaction caused by hydrogen absorption in the palladium (Pd) thin film as a hydrogen absorbing material, and demonstrated using the prototype hydrogen sensor with a microheater and a pair of cantilever SOI thermocouples that this H
2 sensor by this proposed mechanism is surely possible. We have ascertained that the sensor output voltage is increased as the H
2 concentration is increased, that the exothermic reaction ceases after finish of the hydrogen absorption, the exothermic reaction by hydrogen absorption occurs even in pure N
2 gas, that larger output voltage is observed for lower ambient temperature even under no oxygen gas, and that this hydrogen sensor does not respond to the CH
4 gas. We have found that the detection of H
2 concentration based on the exothermic reaction is preferred to carried out after heating the sensing region rather than during heating it especially in lower H
2 concentration than about 5 vol.%, because we can use the null method to detect the extremely low H
2 concentration.
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