Development of the UV-blocking ETFE film (ETFE is a fluoropolymer) for greenhouses is examined, focusing on the production process sequence from synthesizing the filler, to treating the surface, forming the dispersive compounding, extruding the film and applying the anti-drip coating. The weathering resistance of the film is also discussed. The new UV-blocking filler (CeO
2: SiO
2 = 40:60), the treatment agent for dispersion, and the processing method that was devised for the ETFE resin were developed. This UV-blocking film is transparent and after 12 years, the deterioration in UV-blocking function was less than 4% and its mechanical property remained almost unchanged. That success is attributable to the technology used in synthesizing silica-coated cerium dioxide in the solution layer for transparency, performing the silica-coating process in the solution layer for weathering resistance, and developing the dispersion technique so that the filler can be dispersed uniformly in the ETFE resin.
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