Leaching reaction of chromite in H
2SO
4 with K
2Cr
20
7 as an oxidizing agent was studied.
Since it was found that for the dissolution of chromite in H
2SO
4, the oxidation of ferrous iron in the ore to ferric state was an important factor, the extraction of Cr was restricted by the ratio of FeO content in the ore to the theoretical amount derived from Cr
20
3 content. The FeO ratio of the high grade ore (Cr
2O
3 43.95%, FeO 18.70%) was 90% and the low grade ore (Cr
2O
3 37.41%, FeO 11.66%) was 66%. The extraction of Cr of the high grade ore was 94.5%, but with the low grade ore, it was only 46.1% under the same conditions as the high grade ore, due to the low FeO ratio.
An experimental equation on the rate of leaching was given by
y= α√θ—βθ
where
y is the extraction of Cr, θ is the leaching time and α, β are constants. It was considered that the rate process would be the diffusion in particles.
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