When copper converter slag is used as a raw material for iron smelting, copper and zinc in the slag must be removed as much as possible.
In this experiment, the differences of chloridizing process of Cu
2S, Cu
2O, ZnS and ZnO have been investigated for the weight change by chloridizing roasting and X ray diffraction of roasted samples. Chlorine was obtained by decomposition of CaCl
2·2H
20 or NaC1 mixed in the samples.
The obtained results are summarized as follows.
(1) When Cu
2S samples are roasted in the air, CaCl
2 is converted to CaSO
4 and Cu
2S is converted to CuCl by following equation.
Cu
2S+ CaCl
2+2O
2= 2CuCl+ CaSO
4 The volatilization temperature of CuCI formed by roasting is about 600°C.
(2) When the similar samples are roasted in the pure oxygen, Cu
2S is coilverted to CuO at 400-500°C by following reaction. Cu
2S+ CaCl
2+ 30
2= 2CuO+CaSO
4+Cl
2 CuO is converted to CuCl at 500°C.
(3) The formation rate and volatilization rate of CuCl will be balanced at about 600°C.
(4) ZnCl
2 is volatilized as soon as it is formed from ZnS or ZnO.
(5) Chloridization temperature of oxides is about 100-150°C higher than that of sulphides.
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