The mechanism on the formation of Zn
2SnO
4 was investigated as a fundamental study for zinc recovery from the reverberatory furnace dust in tin smelting process. The formation of Zn
2SnO
4 from ZnO and SnO
2 was observed at the temperature higher than 1000°C. The formation yield increases rapidly with increasing the reaction temperature. The experimental results indicate that the formation of Zn
2SnO
4 occurs on the surface of SnO
2 with the diffusion of ZnO. The excess SnO
2, therefore, raises the formation yield of Zn
2SnO
4 and excess ZnO does not affect on it. Heat treatment of ZnO and SnO
2 before the formation reaction gives no influence upon the formation yield of Zn
2SnO
4 unless the reaction temperature is lower than the temperature of heat treatment. It is also revealed that the SiO
2 tends to lower the formation yield of Zn
2SnO
4 because it combines with ZnO preferentially.
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