The extraction rate of lead oxide in the glassy lead silicates containing 0 to 65 mol SiO
2 has beenmeasured by using saturated solution of ammonium nitrate.
The activities of PbO in the silicates are calculated on the assumption that the lead oxide in thesilicate will obey Raoult's law when the extraction rate of lead oxide is 100%. It is found that these resultsindicate almost the same tendency as others.
The activities of PbO in ternary mixtures, containing one of various metallic oxides such as MgO, CaO, ZnO, BaO, TiO
2, Al
2O
3 and Fe
2O
3 in PbO-SiO
2 system, were obtained by using the above method. At constant PbO mole fraction, basic oxide tends to raise the activities of PbO in the range of compositionsinvestigated, whereas acidic oxides lower them.
Moreover, the activies of Cu
2O in the Cu
2O-SiO
2 mixture were calculated from the extraction rateof Cu
2O using KCN solution, which results indicate that Cu
2O-SiO
2 mixtures behave as an ideal solution.
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