Pyrite cinder can be used as a source for iron smelting by removing the impurities such as copper, zinc, etc.
The chloridization and sintering treatment was carried out using three kinds of pyrite cinder whose kind and roasting condition were different. Volatilization percentage of valuable metals, the crushing strength ratio (crushing strength of calcined pellet/crushing strength of drying pellet at 100°C) and the apparent specific gravity of pellet were measured. Mineralogical forms of sintering pellets were also discussed by XMA analysis.
The experimental results are summerized as follows;
(1) Volatilization percentage of Cu, Pb and Zn in pyrite cinder amounts to constant value when heating temperature is above 1100°C, and the volatilization percentage of Pb is the highest for all pyrite cinder. However, in order to use as the material for iron blast furnace, heating temperature shall be desired above 1200°C considering amount of residual S and Cl in pellet.
(2) It was clarified that the kinds of pyrite cinder had influenced on volatilization percentage. As the crushing strength ratio of pellet was greater, the volatilization percentage was inversely lower.
(3) Volatilization percentage is increased by slow heating as compared with rapid heating. However, when heating temperature is 1300°C, this effect is not observed in evidence. When the air flow is an optimum condition, the highest volatilization percentage is obtained and it is closely related to the crushing strength ratio and the apparent specific gravity of pellet.
(4) The relation between compound form of valuable metals in pyrite cinder and roasted pellet was clarified by XMAanalysis. The ring layer was formed by CaCl
2 during chloridization process, it was discussed that formation of this ring layer was the parameter which indicated the degree of chloridization and sintering of pellet.
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