The molten salts of sodium fluoride-calcium fluoride-barium fluoride-aluminum fluoride quaternary system, are known as “Hurter's bath” and “Sumitomo's bath” forelectrolytic refining of aluminum.
1) The densities of the molten salts of sodium fluoride-calcium fluoride-aluminum fluoride ternarysystem were determined in a wide range of composition. The densities changed in a range from 2.0 to 2.3g/cc at 950°C, and increased with the increase in thecontent of calcium fluoride.
2) In this ternary system, the compound NaCaAIF
6 is assumed to have been formed according to the following reaction;
NaAlF
4+ CaF
2=NaCaAlF
63) When the content of calcium fluoride is kept in constant, the maximum density is observed at the composition that the mol ratio of sodium fluoride and aluminum fluoride corresponds to 3:1 (Na
3AIF
6) after the displacement reaction has occurred.
4) The densities of the molten salts of thequaternary system at 950°C changed in a range 2.3 to 3.2g/cc.
The density change has the same tendency as that of the molten salts of the above-mentioned ternary system.
5) In this quaternary system, it has been assumed that the formation of the compound NaBaAIF
6 has priority to the formation of NaCaAIF6.
6) Calculated densities, assuming the additivity of the density of each salt and theformation of compound NaCaAIF
6 and NaBaAIF
6, accord well with measured ones in ternary and quaternary systems respectively.
7) Isothermal liquidus line diagram of this quaternary system has a likeness to that of NaF-BaF
2-AIF
3 ternary system when the content of calcium fluoride is kept constant, but the melting temperatures are lower than the latter on the whole. And the melting temperatures of two composition ranges are about 750°C.
8) We think that we can use some other compositions of this quaternary moltensalts besides Hurter's or Sumitomo's bath as an electrolyte of aluminum refining.
抄録全体を表示