The arsenic problem in nonferrous smelters should be solved as soon as possible. The present work was undertaken from the view point of hydrometallurgical treatment of by-products containing arsenic. It is well-known that the coprecipitation with ferric hydroxide is the most economical method of separating arsenic from aqueous solution. We found that arsenic in solution should be the pentavalent arsenic species for removing arsenic completely from solution over the wide range of pH by the ferric hydroxide coprecipitation. Accordingly, the oxidation of arsenite to arsenate by oxygen, hydrogen peroxide and ozone has been investigated. The results obtained are as follows:
1) The concentration of arsenic in the solution after coprecipitation is considerably reduced over the wide range of pH with increasing the relative amount of Fe (III) added to As (V). Atthe Fe (III) to As (V) molar ratio of 2, the concentration of arsenic in the solution was less than 0.3mg/
lover the pH range of 3.1 to 5.0. At the Fe (III) to As (V) molar ratio of 5, the pH range over which the concentration of arsenic in the solution was less than 0.3mg/
lwas 3.1 to 7.7.
2) Oxygen is not useful as an oxidizing agent for arsenite. Arsenite was oxidized to arsenate by oxygen only when cupric ion was present at high pH (11.2).
3) Arsenite is effectively oxidized to arsenate by hydrogen peroxide (H
2O
2/A
s (III) molar ratio=2) in ammoniacal solutions (pH>9.3), but the-oxidation was slowed down with a decrease in pH, because hydrogen ion liberated with the progress of the oxidation reaction. Therefore an addition of some buffers is effective in the oxidation of arsenite. The oxidation is accelerated with increasing temperature. At 80°C, arsenite was completely oxidized to arsenate even at low pH (3.0).
4) Ozone is an effective oxidizing agent. Arsenite was oxidized rapidly and completely to arsenate by ozone over the wide pH range of 1.0 to 11.0. The oxidation reaction was little affected by pH, temperature and the cupric ion presence.
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