Chemical inter-diffusion coefficients of sulfur, selenium and tellurium in liquid _silver have been measured with the modified capillary reservoir method in the temperature range from 1, 000°C to 1, 300°C.
Several liquid Ag-S, Ag-Se and Ag-Te alloys ranging in composition from 0.2 to 0.8wt% S, from 0.5 to 3.0wt% Se and 5wt% Te were used as the liquid alloys for reservoir. Results obtained in the present investigation are summerized as follows:
1. The diffusion data fit the following Arrhenius type equations in the temperature range from 1, 000°to 1, 300°C
for sulfur
Dc=6.0×10
-3exp (-11500/RT) cm
2/sec Q=11.5±1.0kcal/mole for selenium Dc=1.9×10-3exp (-10300/RT) cm
2/sec Q=10.3±1.2kcal/mole for tellurium Dc=9.9×10-4exp (-9200/RT) cm
2/sec Q=9.2±1.8kcal/mole
2. The diffusivity increases (Ds>Dse>DTe) with the decreasing radius of diffusing particle (rS<rSe<rTe). it is indicating that the size of diffusing particle is of the important factor for inter-diffusion.
3: From the results obtained in this study and the previous one, it has been found that the rate of transportation of void or the re-distribution rate of free volume should be considered for the derivation of theoretical equation for inter-diffusion, as well as the size factor of solute.
4. Apparent activation energy for inter-diffusion may be expressed as the sum of the activation energy of self-diffusion of solvent and the interaction energy between solute and solvent. Values calculated from the following equation agreed very well with the experimental values.
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