In order to obtain the fundamental data for the extraction of nickel from silicate ores, the synthesis of nickel olivine and the reduction of the olivine with hydrogen were studied. A comparison between the results for synthesized materials and those for ores was also revealed.
The results obtained are as follows:
1) The nickel-olivine shows the orthorhombic lattice which has the general formula (Mg
m/2Ni
n/2)
2SiO
4, where
m plus
n equals two, and
m and
n are the integers from zero to two. Ni
2SiO
4 and Mg
2SiO
4 form a complete solid solution at any composition.
2) It is found that the reducibility of Ni
2SiO
4 decreases as the content of Mg
2SiO
4 in the mineral increases.
3) When garnierite is heated in the air, anhydrous nickel silicate, 3 (Mg, Ni) O·2Si0
2, is formed due to the release of the water of crystallization between 460°C and 700°C.
This silicate tends to crystallize at higher temperatures than 800°C, forming forsterite and Si0
2. Nickel oxide in the mineral forms then nickel orthosilicate, and a complete solid solution with forsterite as the synthesized olivine does.
4) The anhydrous nickel silicate is amorphous and reducible. In order to avoid the formation of unreducible compounds of nickel, (Mg
m/2Ni
n/2)
2SiO
4, a regulated slow cooling of the ores from 460°C up to 800°C under hydrogen reducing atmosphere is preferable.
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