Activities of P
bO in the molten P
bO-S
i0
2, P
bO-S
i0
2-C
aO and P
bO-S
i0
2-Al
20
3 systems were determined by e. m. f. measurementes employing solid electrolytes.
These experiments were carried out at the temperature range of 900°-1, 050°by means of the following galvanic cells. Ni, NiO (s)/zr-ca-O/Pb, PbO-SiO
2 (1) Ni, NiO (s)/Zr-Ca-O /Pb, PbO-SiO
2-CaO (1) Ni, NiO (s)/zr-ca-O/Pb, PbO-SiO
2-Al
2O
3 (1)
From these experimental results, it has been shown that the activity of PbO in the molten PbO-SiO
2 system had large negative deviation from Raoult's law and was in a good agreement with previous reliable values and the activity of PbO was considerably increased with increasing of CaO content and was increased slightly by the addition of Al
20
3.
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