In order to find the effect of phosphorus vapor on the gasification of graphite and coke in carbon dioxide, the gasification rates of electrode graphite and metallurgical coke in CO
2-CO-Ar gas mixture were measured in the temperature range of 900-1 000°C at atmospheric pressure. The rate of gasification decreased with increasing the partial pressure of phosphorus. Phosphorus was found to have strong retardation effect.
The experimental result were interpreted by use of Langmuir-Hinshelwood type reaction mechanism (
R=
k1PCO22/1+
k1/
k2RCO22+
k3PCO+
k4Pp) and the rate constants k
1, k
2 and the adsorption coefficients K
3, K
4 were obtained as follows.
For electrode graphite ;
k1=exp (17.78-65 851.2/
RT) (mol/min · atm· g-c),
k2=exp (9.585-24 578/
RT) (mol/min · g-c),
k3 = exp (-13.74 + 38, 108.3/
RT) (atm
-1), and
K4=exp (-8.53 + 43 235.6/
RT) (atm
-1), and for metallurgical coke ;
k1=exp (20.49-68 350/
RT) (mol/min · atm · g-c),
k2=exp (5.478-14 405/
RT) (mol/min · g-c),
K3 =esp (-8.30 +23 330/
RT) (atm
-1), and
K4=exp (-3.92 +31 704.7/
RT) (atm
-1).
Activation energies for
k1, with electrode graphite and metallurgical coke are obtained 65.85kcal/mol and 68.35kcal/mol respectively.
抄録全体を表示