Journal of Environmental Conservation Engineering
Online ISSN : 1882-8590
Print ISSN : 0388-9459
ISSN-L : 0388-9459
Volume 36, Issue 3
Displaying 1-4 of 4 articles from this issue
  • Yasuhiko TAKUMA, Shigeru KATO, Toshinori KOJIMA
    2007Volume 36Issue 3 Pages 198-205
    Published: March 20, 2007
    Released on J-STAGE: December 25, 2008
    JOURNAL FREE ACCESS
    Soil and groundwater pollution from trichloroethylene has recently been noted. In the present work kinetics for decomposition of trichloroethylene using Fenton's reaction are discussed. This study found that the reaction was first-order for concentration of trichloroethylene, 0.8-order for concentration of iron ion and half-order for concentrations of hydrogen peroxide. The reaction rate constant was given as 0.205 (l · mol-1) 1.3 · s-1. Additional experiments were carried out in the presence of humic acid (HA), the most abundant organic compound in soil. The reaction with HA was first-order for concentrations of trichloroethylene and Fe (II) iron, and 0.8-order for concentration of hydrogen peroxide, and the reaction rate constant was 0.865 (l · mol-1) 1.8 · s-1. In spite of small difference in reaction order, these reaction rates are almost the same with and without humic acid under the present conditions.
    At the initial stage of these reactions, concentrations of trichloroethylene were found to be reduced rapidly. The correlation to calculate the reduction amounts is proposed. Finally, equations to predict the variation of trichloroethylene concentration using Fenton's reaction are suggested.
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  • Seiichi TORIYAMA, Takayuki KONDO, Hideichi OKUMURA, Susumu FUJISAKI, S ...
    2007Volume 36Issue 3 Pages 206-213
    Published: March 20, 2007
    Released on J-STAGE: December 25, 2008
    JOURNAL FREE ACCESS
    The amount of annual average dry deposition of SO42-, NO3-, NH4+, Cl-, Ca2+, Mg2+, K+, Na+ at Toyama Prefecture were estimated to be 3.5∼8.1, 0.42∼4.7, 6.5∼12, 0.38∼1.4, 0.42∼0.85, 0.31∼0.94, 0.23∼0.69, 4.1∼8.4 mmol/m2/year, respectively.
    The influence of the Miyake Island volcanic eruption on Toyama Prefecture was detected in the monthly variation of the amount of dry deposition. The amount of dry deposition of nssSO42- in September 2000 reached a maximum value of 23mmol/m2/year.
    The amount of dry deposition of Ca2+ showed the maximum in spring. This (is/might be) caused by the influence of yellow sand. In this season, the amount of dry deposition of other ions was also more than other seasons. In winter, the amount of dry deposition of nssSO42- and NO3- were small. In summer, the amount of dry deposition of Ca2+, K+, Na+, and Mg2+ showed a tendency to be slightly low.
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