The behaviors of N
2O, NO and NH
3 in N
2O-NH
3-N
2 and NO-NH
3-N
2 mixture under the UV irradiation were studied at room temprature. The decomposition rate of NH
3 in NH
3-N
2 mixture under the UV irradiation was proportional to the concentration of NH
3, and the rate under a low pressure mercury lamp irradiation was three times larger than that under a high pressure mercury lamp irradiation. No effect of NH
3 and N
2O was observed on the decomposition rate of N
2O and NH
3 under the irradiation with a low pressure mercury lamp. While N
2O did not change and NH
3 decomposed slowly by the irradiation with a high pressure mercury lamp, and the rate was not affected by N
2O.
NO and NH
3 in NO-NH
3-N
2 mixture decomposed rapidly with the formation of small amount of N
2O as a by-product under a low pressure mercury lamp irradiation. The amount of NO decomposed was nearly equal to that of NH
3, the rate of decomposition of NH
3 increased with the increase of the concentration of NO, and was expressed by the following equation:
d [NH
3] /
dθ=
k1 [NH
3] +
k2 [NH
3] [NO]
1/2 [θ;
W/F (watt⋅min⋅l
-1) ]
The decomposition rate of NO in NO-NH
3-N
2 mixture under a low pressure mercury lamp irradiation was nearly equal to the decomposition rate of NH
3, and was ten times larger than that under a high pressure mercury lamp irradiation. The yield of N
2O (less than 10% of the amount of NO decomposed) increased proportionally to the amount of NH
3 decomposed and the concentration of NO.
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