The behaviors of NO
x and NH
3 in the UV reaction of NO-NH
3-O
2-N
2 mixture were studied at room temperature. The decomposition rate of NH
3 under a high pressure mercury lamp irradiation was proportional to the concentration of NH
3 and was not affected by the presence of NO and O
2. NO reacted with NH
2 formed by the dissociation of NH
3 to form N
2 and was partially oxidized to NO
2. A small amount of N
2O formed as by-product similarly in the case of the absence of NO. The decomposition rate of NO
x was nearly equal to that of NH
3. Under a low pressure mercury lamp irradiation, the decomposition rate of NH
3 increased by the presence of NO and O
2. The rate increased with the increasing of the concentration of O
2. The promotion effect of NO on the NH
3 decomposition decreased with the increasing of the concentration of O
2, while no effect of NO was observed at 10 % of O
2. About 22 % of NH
3 changed to N
2O at 10 % of O
2 and a part of NO was oxidized to NO
2. NO reacted mainly with NH
3 and decomposed to N
2 and H
2O rapidly. The initial decomposition rates of NH
3 and NO
x under a low pressure mercury lamp irradiation were 10 times larger than those under a high pressure mercury lamp irradiation, and the decomposition rate of NH
3 was about 1.3 times of that of NO
x because of the change to N
2O.
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