Dielectric breakdown mechanism of Hafnium (Hf) silicate film has been discussed, on the basis of the temperature dependence of the charge-to-breakdown (Q
bd). It has been found that the activation energy of Q
bd as a function of reciprocal temperature was around 0.1 eV, irrespective of the injection direction of electrons. The activation energy of Q
bd for Hf-slicate gate dielectrics is almost same as that for silicon-dioxide (SiO
2). Furthermore, it was found that Q
bd for Hf-silicate was remarkably small, compared with that for SiO
2.
On the basis of the experimental results, the dielectric breakdown model for Hf-slicate dielectrics is proposed in this paper. It is inferred that, in high temperatures, the dominant mechanism for the dielectric breakdown is the hydrogen-related process, irrespective of the material of the gate dielectrics. We consider that a large amount of the defects in Hf-silicate films brings about the relative small life-time, compared with that with SiO
2.
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